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"Icelike" crystals

Posted on 5/8/10 at 5:33 pm
Posted by baytiger
Boston
Member since Dec 2007
46978 posts
Posted on 5/8/10 at 5:33 pm
I'm pretty good at science but I have no idea what that's supposed to mean.

The water at 5000m is probably between 0-1C, but seawater doesn't freeze until just over -2C, so it can't be ice, can it? Anyone who knows anything care to comment?
Posted by YatTigah
Lakeview, New Orleans, LA
Member since May 2010
517 posts
Posted on 5/8/10 at 5:34 pm to
frozen methane.

i'd imagine the next idea is to take the ROV that was injecting dispersant at the wellhead and use it to inject something inside the box to keep it from freezing up but i have no idea what exactly that would be
Posted by Sid in Lakeshore
Member since Oct 2008
41956 posts
Posted on 5/8/10 at 5:40 pm to
quote:

: "Icelike" crystals


Gas Hydrates

Glycol (anti-freeze) is usually used to combat this.
Posted by baytiger
Boston
Member since Dec 2007
46978 posts
Posted on 5/8/10 at 5:48 pm to
of course. thanks guys.
Posted by ATL TGR
Houston
Member since Apr 2008
2878 posts
Posted on 5/8/10 at 5:59 pm to
quote:

anti-freeze


Always a good thing to disperse into the ocean
Posted by COTiger
Colorado
Member since Dec 2007
16844 posts
Posted on 5/8/10 at 6:11 pm to
Would you prefer antifreeze or crude oil?
Posted by Sid in Lakeshore
Member since Oct 2008
41956 posts
Posted on 5/8/10 at 6:19 pm to
They make biodegradable anti-freeze....not at all knowledgeable about the toxicity of this stuff though.

In a trade-off, I would take a little anti-freeze over a lot of oil.

also heard methanol may be used.....
Posted by C
Houston
Member since Dec 2007
28172 posts
Posted on 5/8/10 at 6:21 pm to
quote:

Would you prefer antifreeze or crude oil?


Probably crude oil, but why not put in a heat exchanger instead? I know time is not on their side, but it would seem like the better option.
Posted by COTiger
Colorado
Member since Dec 2007
16844 posts
Posted on 5/8/10 at 6:23 pm to
quote:

In a trade-off, I would take a little anti-freeze over a lot of oil.


That's what I was thinking.
Posted by ottothewise
Member since Sep 2008
32094 posts
Posted on 5/8/10 at 6:28 pm to
if you read the description of the cause of the bubble, it was these same crystals which caused the incident.
Posted by jeffsdad
Member since Mar 2007
24185 posts
Posted on 5/8/10 at 6:44 pm to
So I am guessing maybe "heat coils" are whatever else that my generate that type of heat may also possibly cause an explosion? It would almost have to be some type of antifreeze?
Posted by Sid in Lakeshore
Member since Oct 2008
41956 posts
Posted on 5/8/10 at 6:49 pm to
Heatting would work, if the box was fitted with heatters. I have seen nothing to suggest this.
Posted by Volvagia
Fort Worth
Member since Mar 2006
52926 posts
Posted on 5/8/10 at 7:24 pm to
Folks, some of you are reacting to the ecological implications of the word antifreeze being used. In connotation, you are thinking is the one specifically used in cars (ethylene glycol) and the associated toxicity.

But the term was intended literally, any additive that lowers the freezing point significantly (any solute lowers the freezing point of water, this is why they salt icy roads and sidewalks).

The two first candidates that pops to mind are are propylene glycol and polyethylene glycol, both of which I would have zero reservations about ingesting myself and in the case of the latter, I have actually drunk a decently concentrated solution containing 20-30% of PEG by the gallon.

Edit: actually the more I think of it, the more I think PEG is the likelist suspect. It imparts a high density to the water solution so they won't have to fight diffusion as much, and I know it is an effective antifreeze because I've used it as a cryoprotectant/stabilizer when I needed a biological sample to stay liquid in spite of the LO2 vapor I was pumping on it to keep it cold.
This post was edited on 5/8/10 at 7:42 pm
Posted by Volvagia
Fort Worth
Member since Mar 2006
52926 posts
Posted on 5/8/10 at 7:30 pm to
quote:

if you read the description of the cause of the bubble, it was these same crystals which caused the incident.


Link please

kthx
Posted by Oyster
North Shore
Member since Feb 2009
10224 posts
Posted on 5/8/10 at 8:43 pm to
I saw where the sea floor temp is 42 degrees F. They were planning to add methanol to the box to prevent this from happening. Not sure what happened to that plan.
This post was edited on 5/8/10 at 9:17 pm
Posted by JudgeHolden
Gila River
Member since Jan 2008
18566 posts
Posted on 5/8/10 at 10:45 pm to
How much methanol would you have to add to a flow this large to keep the methane/water mix from freezing up? Also, won't the temperature drop substantially as the oil goes through the opening at the top and depressurizes? Isn't that just like an aerosol can getting cold as you spray it? What a mess.
Posted by Rick Rickles
Houston, TX
Member since Jan 2006
6240 posts
Posted on 5/8/10 at 10:53 pm to
I'm in Houma at the EOC working the boom management team for the LANG.

Methanol will be injected into the system in the coming hours to see if we can't get this thing to work. If not, another containment system is being built. I will update on the issue as I get news.
Posted by DaphneTigah
Flying under the radar.
Member since Dec 2007
4993 posts
Posted on 5/8/10 at 11:03 pm to
Thanks Rick.. Please update as soon as you know something.
Posted by Luke4LSU
Member since Oct 2007
11986 posts
Posted on 5/8/10 at 11:10 pm to
This whole board is filled with so much god damn STUPID that it makes me want to frickING throw up!

None of you fricking idiots who think you have a clue what you're talking about know shite.

The "icelike crystals" are hydrates, they're inhibited with methanol or LDHI. And are dissolved with either a reduction inpressure or an increase in temperature.

frick!
Posted by Rick Rickles
Houston, TX
Member since Jan 2006
6240 posts
Posted on 5/8/10 at 11:15 pm to
quote:

This whole board is filled with so much god damn STUPID that it makes me want to frickING throw up!

None of you fricking idiots who think you have a clue what you're talking about know shite.

The "icelike crystals" are hydrates, they're inhibited with methanol or LDHI. And are dissolved with either a reduction inpressure or an increase in temperature.

frick!


Um, simmer down.

I think I know what I am talking about since I have 8am conference calls each morning with the BP logistics and operations professionals working this thing.

Methanol is being attempted. Next update 8am tomorrow. Will post success or failure then.
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