Can you have 2 separate Wii units connected to 2 TVs?

Do you mean Wii units? Yes, you can.

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I think you can have 10 different devices one 1 netflix account.

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That's what I've read but I swear I've accessed my account on a about 20 different devices.

With one standard streaming account you can access Netflix on 2 of those devices at a time and if you move up to the expanded streaming you can get 4 devices to stream at a time.