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Question regarding flammable material reacting to anything that touches it

Posted on 6/28/17 at 5:30 pm
Posted by JOHNN
Prairieville
Member since Nov 2008
4362 posts
Posted on 6/28/17 at 5:30 pm
This might be simple to answer but Im not really a science guy so here goes. We picked up 6k gals of natural gas condensate/water mixture today and everything seemed normal when looking at it. But when we went to sample the material, it started instantly bubbling once the surface was broken. At first we went to sample with an aluminum sample tube and it instantly bubbled. So then we tried a plastic sampling tube and same reaction. So then I inserted a wooden measuring stick and the same thing happened again.

What has me stumped is the fact that the material will be perfectly calm, but once the surface is broken it starts bubbling. As you put the sample tube further into the tank, it bubbles more and more, where it basically looks like its boiling (but obviously not). But once you remove said object, it instantly stops. Does this have to do anything with the atmospheric pressure of the material? Or am I way off here?

Thanks in advance for the help.
Posted by MottLaneKid
Gonzales
Member since Apr 2012
4543 posts
Posted on 6/28/17 at 5:35 pm to
Co2 ? Ch4 +O2 = 4H2O + Co2
This post was edited on 6/28/17 at 5:39 pm
Posted by DonChowder
Sonoma County
Member since Dec 2012
9249 posts
Posted on 6/28/17 at 5:37 pm to
quote:

We picked up 6k gals of natural gas condensate/water mixture today

That's the most puzzling part of this story.
Posted by JOHNN
Prairieville
Member since Nov 2008
4362 posts
Posted on 6/28/17 at 5:39 pm to
While it might sound redundant, its just a mixture of gas and water.
Posted by lathoroughbred
Louisiana/Kentucky
Member since May 2008
8094 posts
Posted on 6/28/17 at 5:40 pm to
Gas breaking out of the water?
Posted by DownshiftAndFloorIt
Here
Member since Jan 2011
66763 posts
Posted on 6/28/17 at 5:44 pm to
Yea. The surface tension on the water is probably enough to keep the gas in suspension and breaking it allows it to start bubbling.
Posted by Btrtigerfan
Disgruntled employee
Member since Dec 2007
21375 posts
Posted on 6/28/17 at 5:45 pm to
I think it is a reaction to the different temperature of the sampling materials.

What temperature is your condensate?
Posted by CapperVin
Member since Apr 2013
10531 posts
Posted on 6/28/17 at 5:46 pm to
you ever hear of something called oxygen?

Posted by weadjust
Member since Aug 2012
15082 posts
Posted on 6/28/17 at 5:48 pm to
I can make bubbles with gas and water
Posted by TigerstuckinMS
Member since Nov 2005
33687 posts
Posted on 6/28/17 at 5:55 pm to
quote:

Question regarding flammable material reacting to anything that touches it

Posted by JOHNN
Prairieville
Member since Nov 2008
4362 posts
Posted on 6/28/17 at 6:29 pm to
I think that would make sense. But Im also wondering if it has anything to do with the outside temperature as well. We took a sample around 1pm and the sample has now sat for a few hours inside the office. I just put a pencil inside (to mimic the wooden measuring stick) the sample bottle and no reaction. So I then put an ink pen (to mimic the plastic sample tube) inside and once again no reaction.
Posted by Vdrine
Big Bad Baz
Member since Jun 2014
888 posts
Posted on 6/28/17 at 6:32 pm to
quote:

What has me stumped is the fact that the material will be perfectly calm, but once the surface is broken it starts bubbling. As you put the sample tube further into the tank, it bubbles more and more, where it basically looks like its boiling (but obviously not). But once you remove said object, it instantly stops.


It's like CO2 in soda, the trapped gas doesn't have the energy to break surface tension on its own, but when you stick the probe in that breaks the surface tension and allows the gas to escape. Plus the sample tube has microscopic pits that the trapped gas can enter and that lets it expand, that's why it looked like it was boiling when you stuck the tube further in. Same principle that causes the rapid release of CO2 when you put Mentos in Coke. That's why it's happening, what it means, no clue.
quote:

Does this have to do anything with the atmospheric pressure of the material? Or am I way off here?


The higher the atmospheric pressure the higher the surface tension which means gasses that would normally escape, can't.
Posted by RDOtiger
Zachary
Member since Oct 2013
1146 posts
Posted on 6/28/17 at 6:44 pm to
quote:

The higher the atmospheric pressure the higher the surface tension which means gasses that would normally escape, can't.


Why would there be higher atmospheric pressure? If you're at sea level or 200' higher you would still be at 1atm...I don't see how any place at ground level in La would significantly increase surface tension.

Posted by wallowinit
Louisiana
Member since Dec 2006
14973 posts
Posted on 6/28/17 at 8:49 pm to
That's some funny shite right there.

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